GATE 2012 - Syllabus for Chemistry (XL: Section H)

Graduate Aptitude Test in Engineering - GATE 2012

Last Date : 17 October 2011 (Apply Online)
Start Date : 12 September 2011

Organizing Institute : Indian Institute of Technology Delhi

Graduate Aptitude Test in Engineering (GATE) is an all India examination administered and conducted jointly by the Indian Institute of Science and seven Indian Institutes of Technology on behalf of the National Coordination Board - GATE, Department of Higher Education, Ministry of Human Resource Development (MHRD), Government of India.

Candidates have to Apply only ONLINE. The application fee is Rs 1000/- for GENERAL/OBC/ category and Rs 500/- for SC/ST/PD category candidates.

Date of Online Examination: 29-01-2012 (Sunday)       

Date of Offline Examination: 12-02-2012 (Sunday)

Syllabus for Chemistry (XL: Section H)

(Compulsory Section)

Atomic structure and periodicity:

Planck's quantum theory, wave particle duality, uncertainty principle, quantum mechanical model of hydrogen atom; electronic configuration of atoms; periodic table and periodic properties; ionization energy, election affinity, electronegativity, atomic size.

Structure and bonding:

Ionic and covalent bonding, M.O. and V.B. approaches for diatomic molecules, VSEPR theory and shape of molecules, hybridisation, resonance, dipole moment, structure parameters such as bond length, bond angle and bond energy, hydrogen bonding, van der Waals interactions. Ionic solids, ionic radii, lattice energy (Born-Haber Cycle).

s.p. and d Block Elements:

Oxides, halides and hydrides of alkali and alkaline earth metals, B, Al, Si, N, P, and S, general characteristics of 3d elements, coordination complexes: valence bond and crystal field theory, color, geometry and magnetic properties.

Chemical Equilibria:

Colligative properties of solutions, ionic equilibria in solution, solubility product, common ion effect, hydrolysis of salts, pH, buffer and their applications in chemical analysis, equilibrium constants (K_c, K_p and K_x) for homogeneous reactions,

Electrochemistry:

Conductance, Kohlrausch law, Half Cell potentials, emf, Nernst equation, galvanic cells, thermodynamic aspects and their applications.

Reaction Kinetics:

Rate constant, order of reaction, molecularity, activation energy, zero, first and second order kinetics, catalysis and elementary enzyme reactions.

Thermodynamics:

First law, reversible and irreversible processes, internal energy, enthalpy, Kirchoff's equation, heat of reaction, Hess law, heat of formation, Second law, entropy, free energy, and work function. Gibbs-Helmholtz equation, Clausius-Clapeyron equation, free energy change and equilibrium constant, Troutons rule, Third law of thermodynamics.

Basis of Organic Reactions Mechanism:

Elementary treatment of SN1, SN2, E1 and E2 reactions, Hoffmann and Saytzeff rules, Addition reactions, Markonikoff rule and Kharash effect, Diels-Alder reaction, aromatic electrophilic substitution, orientation effect as exemplified by various functional groups. Identification of functional groups by chemical tests

Structure-Reactivity Correlations:

Acids and bases, electronic and steric effects, optical and geometrical isomerism, tautomerism, conformers, concept of aromaticity